Evaluation of Kinetic Parameters from Steady-State Voltammograms at Ultramicrodisk Electrodes
نویسندگان
چکیده
منابع مشابه
Evaluation technique of kinetic parameters for irreversible charge transfer reactions from steady-state voltammograms at microdisk electrodes
An explicit approximate expression for half-wave potentials of irreversible steady-state current-voltage curves at a microdisk electrode was derived from the diffusion equation and the Butler-Volmer equation on the basis of the previous analytical method (J. E. C., 235 (1987) 87). The plot of the half-wave potential, E1/2, against ln(1-exp(-(E1/2E))F/RT)] showed a linear relation with the slope...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1988
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.61.3417